Crack Attack: Next Day Sealer

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1.
IDENTIFICATION

COMPANY IDENTIFICATION
TechniSoil Global, Inc.
5660 Westside Road
Redding, CA, USA 96001
Product Name: Crack Attack: Next Day Sealer
Revision Date: 5/30/2018
Version: 1
SDS Number: CAS 324
Number: Chemical MIXTURE
Family: Chemical Minerals
Formula: *** PROPRIETARY ***
Synonyms: Mineral Reinforced Inorganic Polymer
Product Use: A single package, water dispersed, polymer modified, slate and mineral filled, black, cementious asphalt coating.

Customer Information Number Toll Free: 877-356-2250

EMERGENCY TELEPHONE NUMBER
24-Hour Emergency Contact: 800-424-9300
Local Emergency Contact: 800-424-9300



2.
HAZARD IDENTIFICATION

NFPA: Health = 1, Fire = 0, Reactivity = 0
HMIS III: H*1/F0/PH0

PERSONAL PROTECTION
Safety Glasses, Gloves,
Dust and Vapor Respirator

GHS Signal Word: DANGER

GHS Classifications:
Health, Skin corrosion/irritation, 2
Health, Serious Eye Damage/Eye Irritation, 2 B
Health, Specific target organ toxicity - Single exposure, 3
Health, Carcinogenicity, 2
Health, Specific target organ toxicity - Repeated exposure, 2

GHS Phrases:
H315 - Causes skin irritation
H320 - Causes eye irritation
H335 - May cause respiratory irritation
H351 - Suspected of causing cancer
H373 - May cause damage to organs through prolonged or repeated exposure

GHS Precautionary Statements:
P260 - Do not breathe dust.
P262 - Do not get in eyes, on skin, or on clothing.
P264 - Wash skin thoroughly after handling.
P270 - Do not eat, drink or smoke when using this product.
P271 - Use only outdoors or in a well-ventilated area.
P280 - Wear protective gloves/protective clothing/eye protection/face protection.
P302+352 - IF ON SKIN: Wash with soap and water.
P304+340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+351+338 - IF IN EYES: DO NOT RUB. Rinse continuously with water for several minutes. Remove contact lenses if present and easy to do. Continue rinsing.
P312 - Call a POISON CENTER or doctor/physician if you feel unwell.
P333+313 - If skin irritation or a rash occurs: Get medical advice/attention.
P337+313 - If eye irritation persists: Get medical advice/attention.
P362 - Take off contaminated clothing and wash before reuse.
P501 - Dispose of contents/container to an approved waste disposal plant.



3.
COMPOSITION / INFORMATION ON INGREDIENTS

Ingredients:
Cas # I Percentage I Chemical Name

1317-65-3 I 59-79% I Proprietary, non-hazardous, non-regulated
8052-42-4 I 10-20% I Asphalt
14808-60-7 I 10-20% I Silica, crystalline quartz
1333-86-4 I <1.0% I Carbon black



4.
FIRST AID MEASURES

Inhalation: Blow nose to remove substance from nasal passages. Give oxygen or artificial respiration if needed. If symptoms develop, move victim to fresh air. If symptoms persist, obtain medical attention.
Skin Contact: Wipe/brush off as much chemical as possible from skin BEFORE flushing skin with water. Promptly flush skin with water for at least 15 minutes to ensure all chemical is removed. If reddening and/or a rash develops and/or persists, obtain medical attention.
Eye Contact: Do NOT rub eyes. Flush with large amounts of water for at least 15 minutes, lifting upper and lower lids occasionally. If irritation persists, obtain medical attention.
Ingestion: No need for first aid is anticipated. If symptoms develop, obtain medical attention. Do NOT induce vomiting unless instructed to do so by medical personnel.

Most important symptoms and effects, both acute and delayed: The most important known symptoms and effects are described in the labelling (see Section 2) and/or Section 11. Prolonged inhalation of Silica, crystalline quartz may result in silicosis. Silicosis is a disabling pulmonary fibrosis characterized by fibrotic changes and miliary nodules in the lungs and may be accompanies by a dry cough, shortness of breath, emphysema, decreased chest expansion, and increased susceptibility to tuberculosis. In advanced stages, loss of appetite, pleuritic pain, and total incapacity to work may occur. Advanced silicosis may result in death due to cardiac failure or destruction of lung tissue. Silica, crystalline quartz is classified as Group 1 “Known to be carcinogenic to humans” by the IARC and “Sufficient evidence” of carcinogenicity by the NTP. The chronic health risks are associated with respiring particles of 3-4 microns over protracted periods of time. Currently, there is a limited understanding of the mechanisms of crystalline silica toxicity, including its mechanisms for lung carcinogenicity. Additional studies are needed to determine whether the cell transforming activity of quartz is related to its carcinogenic potential.
Indication of any immediate medical attention and special treatment needed:
No data available.



5.
FIREFIGHTING MEASURES

Flammability: Not flammable
Flash Point: DNA
Flash Point Method: DNA
Burning Rate: No data available
Autoignition Temp: No data available
LEL: DNA
UEL: DNA

Extinguishing Media:
Water Spray
Carbon Dioxide
Alcohol-Resistant Foam

Special Hazards Arising From the Substance or Mixture:
Oxides of Aluminum, Carbon, Calcium, Magnesium, Nitrogen (NOx), Sodium and Sulfur.
Unburnt hydrocarbon particulate.
Trace quantities of Ammonia, Hydrogen Sulfide, Formaldehyde, and 2-aminoethanol.
Temperatures above 870 °C may cause Tridymite to form.
Temperatures above 1,470 °C may cause Cristobalite to form.

Advice for Firefighters:
Firefighters should wear full-face, positive-pressure respirators.

Further Information:
If incinerated, may release toxic fumes.
Small quantities of Hydrogen Sulfide may be released upon heating. Use caution.
Exercise care when using water to extinguish fires, as hot asphalt products may produce steam and violent foaming.
See Section 7 for more information on safe handling.
See Section 8 for more information on personal protection equipment.
See Section 13 for disposal information.



6.
ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures:
Use personal protective equipment, including vapor respirator when handling aqueous product and dust respirator when handling dried product. Avoid dust formation when handling dried product. Avoid breathing dust when handling dried product. Keep from contacting skin or eyes. Ensure adequate ventilation. Evacuate personnel to safe areas.
Environmental precautions:
Prevent further release (leakage/spillage) if safe to do so. Do not allow product to enter drains. Do not allow to drain to environment.

Methods and materials for containments and cleaning up:
Absorb with liquid-binding material (sand, diatomite, universal binders, sawdust). If cleaning up dried product, sweep up, shovel or collect spilage with an electrically protected vacuum cleaner. Pick up and arrange disposal or dried product without creating dust. Place contaminated material into suitable, closed containers for disposal. Dispose of contaminated material according to Section 13. After spillage has been collected, area may be flushed with water or wet-brushed. Ensure adequate ventilation.

Reference to other sections:
Comply with federal, state and local regulations on reporting spills. See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for information on proper disposal.



7.
HANDLING AND STORAGE

Handling Precautions:
Avoid breathing vapors or mist. Avoid formation of dust when handling dried product. Avoid breathing dust when handling dried product. Avoid contact with eyes, skin, or clothing. Keep containers closed when not in use. Do not expose containers to open flame or excessive heat. Do not puncture or drop containers. Handle with care and avoid spillage on the floor. Keep material out of reach of children. Keep material away from incompatible materials. Wash thoroughly after handling. Ensure adequate ventilation.

Storage Requirements:
Keep away from heat, sparks and flames. Store in a dry area. Store away from strong acids, strong bases, strong oxidizing agents, strong reducing agents and Hydrogen Fluoride.



8.
EXPOSURE CONTROLS / PERSONAL PROTECTION

Engineering Controls:
All ventilation should be designed in accordance with OSHA standard (29 CFR 1910.94). Use local exhaust at filling zones and where leakage and dust formation is probable. Use mechanical (general) ventilation for storage areas. Use appropriate ventilation as required to keep Exposure Limits in Air below TLV & PEL limits.

Personal Protective Equipment:
Eye/Face Protection:
When using material use safety glasses, gloves and combined dust/vapor respirator according to HMIS PP, I. All safety equipment should be tested and approved under appropriate government standards such as NIOSH (US) or EN 166 (EU).

Skin Protection:
Handle with gloves made from water-impermeable materials. Barrier creams should not be used in place of gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove’s outer surface) to avoid skin contact. Dispose of contaminated gloves according to applicable laws and laboratory practices.

Body Protection:
Chemically resistant gloves and safety glasses are recommended. Type of protective equipment should be selected based on concentration amount and conditions of use of this material.

Respiratory Protection:
Use of a combined dust/vapor respirator is highly recommended. A full-face dust/ vapor respirator may be required as backup to engineering controls when proper engineering controls are not in place to keep TLV and PEL limits below defined thresholds. All respiratory equipment must either be NIOSH/MSHA-approved (under 30 CFR 11) or NIOSH-approved (under 42 CFR 84).

Control of Environmental Exposure:
Prevent leakage or spillage if safe to do so. Do not let material enter drains.

Components with workplace control parameters:
Component(s): Asphalt; Silica, crystalline quartz; Carbon black
CAS No(s): 8052-42-4; 14808-60-7; 1333-86-4
USA OSHA (TWA/PEL, General Industry): 30 mg/m3 (%SiO2+2, Total Dust, 8 hours)
USA OSHA (TWA/PEL, General Industry): 10 mg/m3 (%SiO2+2, Respirable Fraction, 8 hours)
USA OSHA (TWA/PEL, General Industry): 250 mppcf* (%SiO2+5)
USA OSHA (TWA/PEL, Construction Industry): 250 mppcf* (%SiO2+5)
USA OSHA (TWA/PEL, Shipyard Employment): 250 mppcf* (%SiO2+5)
USA OSHA Occupational Exposure Limits Table Z-1 Limits for Air Contaminants (TWA): 3.5 mg/m3
USA ACGIH (TWA/TLV): 0.025 mg/m3
USA NIOSH (TWA/REL): 0.050 mg/m3
Cal/OSHA (TWA/PEL): 0.10 mg/m3 *mppcf = Millions of particles per cubic foot of air

Biological occupational exposure limits:
Contains no substances with biological occupational exposure limits values.



9.
PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Thixotropic, flowable black liquid
Physical State: Liquid
Odor Threshold: Not determined
Particle Size: Not determined
Spec Grav./Density: 1.318 - 1.678 g/ml (11 - 14 lbs/gal)
Viscosity: Not determined
Sat. Vap. Conc.: DNA
Boiling Point: > 100 °C (212 °F)
Flammability: (solid, gas): Not flammable
Partition Coefficient: Not determined
Vapor Pressure:
pH: @ 100%: 5 - 12
Evap. Rate: (N-Butyl Acetate = 1): Water
Molecular Weight: MIXTURE
Decomp Temp: Not determined
Odor: Asphalt
Molecular Formula: MIXTURE
Solubility: 100%
Softening Point: Not determined
Percent Volatile: <45%
Heat Value: Not determined
Freezing/Melting Pt.: Not determined
Flash Point: DNA
Octanol: Not determined
Vapor Density: (air = 1): Not determined
VOC: <1%
Bulk Density: Not determined
Auto-Ignition Temp: Not determined
UFL/LFL: DNA



10.
STABILITY AND REACTIVITY

Stability: Product is stable under normal conditions.
Conditions to Avoid: Incompatibilities, flames, ignition sources.
Materials to Avoid: Strong acids, strong bases, strong oxidizing agents, strong reducing agents and Hydrogen Fluoride.

Hazardous Decomposition: Oxides of Aluminum, Carbon, Calcium, Magnesium, Nitrogen (NOx), Sodium and Sulfur. Trace quantities of Ammonia, Hydrogen Sulfide, Formaldehyde, and 2-aminoethanol. Temperatures above 870 °C may cause Tridymite to form. Temperatures above 1470 °C may cause Cristobalite to form.
Hazardous Polymerization: Will not occur



11.
TOXICOLOGICAL INFORMATION

Component(s): Asphalt; Silica, crystalline quartz; Carbon black
CAS No(s): 8052-42-4; 14808-60-7; 1333-86-4

Acute Toxicity:
LD50 Oral - Rat: 500 mg/kg
LD50 Dermal - Rabbit: > 2,000 mg/kg

Skin Corrosion/Irritation: Causes skin irritation.

Serious Eye Damage/Eye Irritation: Causes eye irritation.

Respiratory or Skin Sensation: No data available

Germ Cell Mutagenicity: No data available

Carcinogenicity: This product is or contains a component that is classifiable as to its carcinogenicity to humans (Silica, crystalline quartz), and two components that are classifiable as possily carcinogenic to humans (Asphalt, Carbon black )based on their IARC, ACGIH, NTP or OSHA classifications. Limited evidence of carcinogenicity in human studies.

IARC: 1 - Group 1: Carcinogenic to humans (Silica, crystalline quartz); 28 - Group 28: Possibly carcinogenic to humans (Asphalt, Carbon black).
ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH.
NTP: Known to be a human carcinogen (Silica, crystalline quartz).
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA.

Reproductive Toxicity: No data available

Specific Target Organ Toxicity · Single Exposure: No data available

Specific Target Organ Toxicity · Repeated Exposure: Inhalation - May cause damage to organs through prolonged or repeated inhalation exposure when handling dried material.

Aspiration Hazard: No data available

Additional Information:
Component: Asphalt; RTECS: CI9900000
Component: Silica, crystalline quartz; RTECS: VV7330000
Component: Carbon black; RTECS: FF5800000




12.
ECOLOGICAL INFORMATION

Component(s): Asphalt; Silica, crystalline quartz; Carbon black
CAS No(s): 8052-42-4; 14808-60-7; 1333-86-4

Toxicity:
Toxicity to fish:
LC50 - Danio rerio (Zebra Fish): > 1,000 mg/l (96 h)

Toxicity to daphnia and other aquatic invertebrates:
Static Test EC50 - Daphnia magna (Water Flea): > 5,600 mg/l (24 h)

Toxicity to algae:
Static Test EC50 - Desmodesmus subspicatus (Green Algae): > 10,000 mg/l (24 h)

Persistence and Degradability:
No data available

Bioaccumulative Potential:
No data available

Mobility in Soil:
No data available

Results of PBT and vPvB Assessment:
Not required/conducted

Other Adverse Effects:
An environmental hazard cannot be excluded in the event of unprofessional handling or disposal. May be harmful to aquatic life.



13.
DISPOSAL CONSIDERATIONS

Product: Hazardous wastes shall be managed responsibly. All entities that store, transport or handle hazardous waste shall take the necessary measures to prevent risks of pollution, release into the environment or damage to people and animals. Contact a licensed professional waste disposal service to dispose of this material.

Contaminated Packaging: Dispose of as unused product.



14.
TRANSPORT INFORMATION

DOT (US)
Non-regulated material, liquid

IMDG
Non-regulated material, liquid

IATA
Non-regulated material, liquid



15.
REGULATORY INFORMATION

COMPONENT / (CAS/PERC) / CODES

*Asphalt (8052424 10-20%) MASS, NJHS, NRC, PA, PROP65, SARA311/312, TSCA, TXAIR
*Silica, crystalline quartz (14808607 10-20%) MASS, NJHS, NRC, OSHAWAC, PA, PROP65, SARA311/312, TSCA, TXAIR
*Carbon black (1333864 <1.0%) MASS, NJHS, OSHAWAC, PA, PROP65, SARA311/312, TSCA, TXAIR

REGULATORY KEY DESCRIPTIONS
MASS = MA Massachusetts Hazardous Substances List
NJHS = New Jersey Right to Know Hazardous Substances
NRC = Nationally Recognized Carcinogens
OSHAWAC = OSHA Workplace Air Contaminants
PA = PA Right-To-Know List of Hazardous Substances
PROP65 = CA Prop 65
SARA311/312 = SARA 311/312 Toxic Chemicals
TSCA = Toxic Substances Control Act
TXAIR = TX Air Contaminants with Health Effects Screening Level



16.
OTHER INFORMATION

For additional information, refer to the American Conference of Governmental Industrial Hygienists (ACGIH) documentation of TLV’s (Threshold Limit Values) for individual components, Fluoropolymers Safe Handling Guide published by The Society of the Plastics Industry, and the DOT Emergency Response Guidebook. The product is for the industrial use only. We do not guarantee the safety in case the product is used for the other purposes. When using the product for healthcare application or food/feed application, consult us in advance. This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. TechniSoil Global Inc. urges each customer or recipient of this (M)SDS to study it carefully and consult appropriate expertise, as necessary or appropriate, to become aware of and understand the data contained in this (M)SDS and any hazards associated with the product. The information herein is provided in good faith and believed to be accurate as of the effective date shown above. However, no warranty, express or implied, is given. Regulatory requirements are subject to change and may differ between various locations. It is the buyer's/user's responsibility to ensure that his activities comply with all federal, state, provincial or local laws. The information presented here pertains only to the product as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is the buyer's/user's duty to determine the conditions necessary for the safe use of this product. Due to the proliferation of sources for information such as manufacturer- specific (M)SDSs, we are not and cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current, please contact us for the most current version. TechniSoil Global Inc. encourages and expects you to read and understand the entire (M)SDS, as there is important information throughout the document. We expect you to follow the precautions identified in this document unless your use conditions would necessitate other appropriate methods or actions.